Jennifer Garner & Ben Affleck

Jennifer Garner and Ben Affleck first crossed paths on the set of Pearl Harbor and later reunited when they shot Daredevil. It was in this movie that the actor admitted that they fell in love. It was in 2004 that the two stepped out as a couple and in 2005, they were married in a private ceremony. The power couple had three children between them: Violet, Seraphina, and Samuel. It was refreshing to see the A-list stars become the hands-on type of parents.

Sadly, they eventually separated in 2015 but remain on good terms. In fact, they are co-parenting their children and have been spotted together as a family. Garner has already put plenty of investments in her family while she remains a friend to her former husband. The two stars have since dated other people but are both currently single.